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Enantioselective Carbonyl Allylation, Crotylation and tert-Prenylation of Furan Methanols and Furfurals via Iridium Catalyzed Transfer Hydrogenation

[Image: see text] 5-Substituted-2-furan methanols 1a–1c are subject to enantioselective carbonyl allylation, crotylation and tert-prenylation upon exposure to allyl acetate, α-methyl allyl acetate or 1,1,-dimethylallene in the presence of an ortho-cyclometallated iridium catalyst modified by (R)-Cl,...

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Main Authors: Bechem, Benjamin, Patman, Ryan L., Hashmi, Stephen, Krische, Michael J.
Format: Artigo
Jezik:Inglês
Izdano: 2010
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2830394/
https://ncbi.nlm.nih.gov/pubmed/20131774
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo902697g
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