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Enantioselective Carbonyl Allylation, Crotylation and tert-Prenylation of Furan Methanols and Furfurals via Iridium Catalyzed Transfer Hydrogenation
[Image: see text] 5-Substituted-2-furan methanols 1a–1c are subject to enantioselective carbonyl allylation, crotylation and tert-prenylation upon exposure to allyl acetate, α-methyl allyl acetate or 1,1,-dimethylallene in the presence of an ortho-cyclometallated iridium catalyst modified by (R)-Cl,...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2830394/ https://ncbi.nlm.nih.gov/pubmed/20131774 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo902697g |
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