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Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate

[Image: see text] A method for carbonyl allylation and crotylation from the alcohol oxidation state via allyl acetate-alcohol transfer hydrogenative C-C coupling is described. Exposure of allyl acetate to benzylic and allylic alcohols 1a-9a in the presence of an iridium catalyst derived from [IrCl(c...

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Bibliographic Details
Main Authors: Kim, In Su, Ngai, Ming-Yu, Krische, Michael J.
Format: Artigo
Language:Inglês
Published: 2008
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2858451/
https://ncbi.nlm.nih.gov/pubmed/18444616
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja802001b
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