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Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate
[Image: see text] A method for carbonyl allylation and crotylation from the alcohol oxidation state via allyl acetate-alcohol transfer hydrogenative C-C coupling is described. Exposure of allyl acetate to benzylic and allylic alcohols 1a-9a in the presence of an iridium catalyst derived from [IrCl(c...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2858451/ https://ncbi.nlm.nih.gov/pubmed/18444616 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja802001b |
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