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Diastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation()

[Image: see text] Alcohol Solves Problems: Chiral iridium catalysts modified by (R)-SEGPHOS catalyze the transfer hydrogenative coupling of racemic α-cyclopropyl allyl acetate with diverse primary alcohols with good anti-diastereo- and exceptional enantioselectivity. These processes represent the fi...

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Détails bibliographiques
Publié dans:Chemistry
Auteurs principaux: Tsutsumi, Ryosuke, Hong, Suckchang, Krische, M. J.
Format: Artigo
Langue:Inglês
Publié: 2015
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4627847/
https://ncbi.nlm.nih.gov/pubmed/26235369
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201502499
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