Cargando...

Enantioselective Iridium-Catalyzed Carbonyl Isoprenylation via Alcohol-Mediated Hydrogen Transfer

Highly enantioselective iridium catalyzed carbonyl (2-vinyl)allylation or “isoprenylation” is achieved via hydrogen auto-transfer or 2-propanol-mediated reductive coupling from primary alcohol or aldehyde reactants, respectively. Using this method, asymmetric total syntheses of the terpenoid natural...

Descrición completa

Gardado en:
Detalles Bibliográficos
Publicado en:Chem Commun (Camb)
Main Authors: Xiang, Ming, Luo, Guoshun, Wang, Yuankai, Krische, Michael J.
Formato: Artigo
Idioma:Inglês
Publicado: 2019
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6339811/
https://ncbi.nlm.nih.gov/pubmed/30608076
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc09706b
Tags: Engadir etiqueta
Sen Etiquetas, Sexa o primeiro en etiquetar este rexistro!