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Enantioselective Iridium-Catalyzed Carbonyl Isoprenylation via Alcohol-Mediated Hydrogen Transfer
Highly enantioselective iridium catalyzed carbonyl (2-vinyl)allylation or “isoprenylation” is achieved via hydrogen auto-transfer or 2-propanol-mediated reductive coupling from primary alcohol or aldehyde reactants, respectively. Using this method, asymmetric total syntheses of the terpenoid natural...
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| Publié dans: | Chem Commun (Camb) |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6339811/ https://ncbi.nlm.nih.gov/pubmed/30608076 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc09706b |
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