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Diastereo- and Enantioselective anti-Alkoxyallylation Employing Allylic gem-Dicarboxylates as Allyl Donors via Iridium Catalyzed Transfer Hydrogenation
[Image: see text] Enantioselective transfer hydrogenation of gem-dibenzoate 1e in the presence of aromatic, α, β-unsaturated or aliphatic aldehydes 2a–2i mediated by isopropanol and employing a cyclometallated iridium C,O-benzoate derived from allyl acetate, 4-cyano-3-nitrobenzoic acid and (R)-SEGPH...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2824430/ https://ncbi.nlm.nih.gov/pubmed/20099821 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9097675 |
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