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Diastereo- and Enantioselective anti-Alkoxyallylation Employing Allylic gem-Dicarboxylates as Allyl Donors via Iridium Catalyzed Transfer Hydrogenation

[Image: see text] Enantioselective transfer hydrogenation of gem-dibenzoate 1e in the presence of aromatic, α, β-unsaturated or aliphatic aldehydes 2a–2i mediated by isopropanol and employing a cyclometallated iridium C,O-benzoate derived from allyl acetate, 4-cyano-3-nitrobenzoic acid and (R)-SEGPH...

詳細記述

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書誌詳細
主要な著者: Han, Soo Bong, Han, Hoon, Krische, Michael J.
フォーマット: Artigo
言語:Inglês
出版事項: 2010
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2824430/
https://ncbi.nlm.nih.gov/pubmed/20099821
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9097675
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