Enantioselective Allylation, Crotylation and Reverse Prenylation of Substituted Isatins via Iridium Catalyzed C-C Bond Forming Transfer Hydrogenation

Transfer hydrogenation of substituted isatins in the presence of allyl acetate, α-methyl allyl acetate or 1,1,-dimethylallene employing an ortho-cyclometallated iridium catalyst modified by CTH-(R)-P-PHOS provides products of carbonyl allylation, crotylation and reverse prenylation, respectively, in...

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Hlavní autoři: Itoh, Junji, Han, Soo Bong, Krische, Michael J.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2846777/
https://ncbi.nlm.nih.gov/pubmed/19606435
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200902328
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