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Enantioselective Ruthenium Catalyzed Carbonyl Allylation via Alkyne-Alcohol C-C Bond Forming Transfer Hydrogenation: Allene Hydrometallation vs. Oxidative Coupling
Chiral ruthenium(II) complexes modified by Josiphos ligands catalyze the reaction of alkynes with primary alcohols to form homoallylic alcohols with excellent control of regio-, diastereo- and enantioselectivity. These processes represent the first examples of enantioselective carbonyl allylation us...
Αποθηκεύτηκε σε:
| Τόπος έκδοσης: | J Am Chem Soc |
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| Κύριοι συγγραφείς: | , , , |
| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2015
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4385519/ https://ncbi.nlm.nih.gov/pubmed/25734220 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00747 |
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