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Carbonyl anti-(α-Amino)allylation via Ruthenium Catalyzed Hydrogen Auto-Transfer: Use of an Acetylenic Pyrrole as an Allylmetal Pronucleophile
A single ruthenium complex catalyzes two discrete transformations resulting in the net conversion of an acetylenic pyrrole and alcohols to products of carbonyl anti-(α-amino)allylation. An initial catalytic process enables isomerization of an alkyne to a kinetically more reactive allene. A second ca...
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| Publicat a: | Org Lett |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5637530/ https://ncbi.nlm.nih.gov/pubmed/28849663 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b02336 |
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