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Asymmetric Allylation of Glycidols Mediated by Allyl Acetate via Iridium Catalyzed Hydrogen Transfer
Glycidols prepared via Sharpless asymmetric epoxidation participate in asymmetric redox-neutral carbonyl allylation with good levels of catalyst-directed diastereoselectivity. Equally stereoselective allylations may be performed from the aldehyde oxidation level using 2-propanol as the terminal redu...
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| Publié dans: | Org Lett |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2017
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5651674/ https://ncbi.nlm.nih.gov/pubmed/28221810 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b00343 |
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