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Asymmetric Allylation of Glycidols Mediated by Allyl Acetate via Iridium Catalyzed Hydrogen Transfer

Glycidols prepared via Sharpless asymmetric epoxidation participate in asymmetric redox-neutral carbonyl allylation with good levels of catalyst-directed diastereoselectivity. Equally stereoselective allylations may be performed from the aldehyde oxidation level using 2-propanol as the terminal redu...

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Vydáno v:Org Lett
Hlavní autoři: Kim, Seung Wook, Lee, Wonchul, Krische, Michael J.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2017
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5651674/
https://ncbi.nlm.nih.gov/pubmed/28221810
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b00343
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