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Regio- and Enantioselective Iridium-Catalyzed N-Allylation of Indoles and Related Azoles with Racemic Branched Alkyl-Substituted Allylic Acetates
Rough, Ready and Regioselective. Stable to air, water and SiO(2), cyclometallated π-allyliridium C,O-benzoates modified by (S)-tol-BINAP catalyze highly enantioselective N-allylations of indoles and related azoles. Complementing the scope of all previously reported metal-catalyzed indole allylations...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6534432/ https://ncbi.nlm.nih.gov/pubmed/30964961 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201902799 |
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