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Iridium(I)-Catalyzed Regio- and Enantioselective Allylic Amidation

Ir(I)-catalyzed intermolecular allylic amidation of ethyl allylic carbonates with soft nitrogen nucleophiles under completely “salt-free” conditions is described. A combination of [Ir(COD)Cl](2), a chiral phosphoramidite ligand L*, and DBU as a base in THF effects the reaction. The reaction appears...

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Détails bibliographiques
Auteurs principaux: Singh, Om V., Han, Hyunsoo
Format: Artigo
Langue:Inglês
Publié: 2007
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2700766/
https://ncbi.nlm.nih.gov/pubmed/19554202
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2007.08.009
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