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Iridium(I)-Catalyzed Regio- and Enantioselective Allylic Amidation
Ir(I)-catalyzed intermolecular allylic amidation of ethyl allylic carbonates with soft nitrogen nucleophiles under completely “salt-free” conditions is described. A combination of [Ir(COD)Cl](2), a chiral phosphoramidite ligand L*, and DBU as a base in THF effects the reaction. The reaction appears...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2007
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2700766/ https://ncbi.nlm.nih.gov/pubmed/19554202 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2007.08.009 |
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