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Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Silyl Dienolates Derived from Dioxinones

We report Ir-catalyzed, regio- and enantioselective allylic substitution reactions of unstabilized silyl dienolates derived from dioxinones. Asymmetric allylic substitution of a variety of allylic trichloroethyl carbonates with these silyl dienolates gave γ-allylated products selectively in 60–84% y...

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Hlavní autoři: Chen, Ming, Hartwig, John F.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2014
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4214550/
https://ncbi.nlm.nih.gov/pubmed/25223593
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201406778
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