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Iridium-Catalyzed Enantioselective Allylic Substitutions of Aliphatic Esters via Silyl Ketene Acetals
Enantioselective allylic substitutions with enolates derived from aliphatic esters under mild conditions remain challenging. Herein we report iridium-catalyzed enantioselective allylations of silyl ketene acetals, the silicon enolates of esters, to form products containing a quaternary carbon at the...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5677530/ https://ncbi.nlm.nih.gov/pubmed/28597600 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201704354 |
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