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Iridium-Catalyzed Enantioselective Allylic Substitutions of Aliphatic Esters via Silyl Ketene Acetals

Enantioselective allylic substitutions with enolates derived from aliphatic esters under mild conditions remain challenging. Herein we report iridium-catalyzed enantioselective allylations of silyl ketene acetals, the silicon enolates of esters, to form products containing a quaternary carbon at the...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Jiang, Xingyu, Hartwig, John F.
Format: Artigo
Sprog:Inglês
Udgivet: 2017
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5677530/
https://ncbi.nlm.nih.gov/pubmed/28597600
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201704354
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