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Iridium-Catalyzed Enantioselective Allylic Substitutions of Aliphatic Esters via Silyl Ketene Acetals
Enantioselective allylic substitutions with enolates derived from aliphatic esters under mild conditions remain challenging. Herein we report iridium-catalyzed enantioselective allylations of silyl ketene acetals, the silicon enolates of esters, to form products containing a quaternary carbon at the...
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| Vydáno v: | Angew Chem Int Ed Engl |
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| Hlavní autoři: | , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2017
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5677530/ https://ncbi.nlm.nih.gov/pubmed/28597600 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201704354 |
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