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Amphiphilic π-Allyliridium C,O-Benzoates Enable Regio- and Enantioselective Amination of Branched Allylic Acetates Bearing Linear Alkyl Groups
The first examples of amphiphilic reactivity in the context of enantioselective catalysis are described. Commercially available π-allyliridium C,O-benzoates, which are stable to air, water and SiO(2) chromatographically, and are well known to catalyze allyl acetate-mediated carbonyl allylation, are...
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| Gepubliceerd in: | J Am Chem Soc |
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| Hoofdauteurs: | , , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2018
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6262838/ https://ncbi.nlm.nih.gov/pubmed/29350523 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b13482 |
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