Substrate and Lewis Acid Coordination Promote O–O Bond Cleavage of an Unreactive L(2)Cu(II)(2)(O(2)(2−)) Species to Form L(2)Cu(III)(2)(O)(2) Cores with Enhanced Oxidative Reactivity

Ítems similars

• Geometric and Electronic Structure of [{Cu(MeAN)}(2)(μ-η(2):η(2)(O(2)(2−)))](2+) with an Unusually Long O–O Bond: O–O Bond Weakening vs Activation for Reductive Cleavage
  per: Park, Ga Young, et al.
  Publicat: (2012)
• Tuning of the Copper–Thioether Bond in Tetradentate N(3)S((thioether)) Ligands; O–O Bond Reductive Cleavage via a [Cu(II)(2)(μ-1,2-peroxo)](2+)/[Cu(III)(2)(μ-oxo)(2)](2+) Equilibrium
  per: Kim, Sunghee, et al.
  Publicat: (2014)
• Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu(2)O(2) Core with Unexpected Structure and Reactivity
  per: Garcia-Bosch, Isaac, et al.
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• A “Naked” Fe(III)-(O(2)(2–))-Cu(II) Species Allows for Structural and Spectroscopic Tuning of Low-Spin Heme-Peroxo-Cu Complexes
  per: Garcia-Bosch, Isaac, et al.
  Publicat: (2015)
• A Peroxynitrite Dicopper Complex: Formation via Cu–NO and Cu−O(2) Intermediates and Reactivity via O–O Cleavage Chemistry
  per: Cao, Rui, et al.
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