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Advanced 1,1-carboboration reactions with pentafluorophenylboranes
The 1,1 carboboration reaction of a variety of metal-substituted alkynes with simple trialkylboranes R(3)B yields the respective alkenylboranes (Wrackmeyer reaction). The use of the strongly electrophilic R-B(C(6)F(5))(2) reagents allows for much milder reaction conditions and gives good yields of t...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Royal Society of Chemistry
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5508682/ https://ncbi.nlm.nih.gov/pubmed/28757997 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03282b |
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