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Divergent Elementoboration: 1,3‐Haloboration versus 1,1‐Carboboration of Propargyl Esters

This work showcases the 1,3‐haloboration reaction of alkynes in which boron and chlorine add to propargyl systems in a proposed sequential oxazoliumborate formation with subsequent ring‐opening and chloride migration. In addition, the functionalization of these propargyl esters with dimethyl groups...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Wilkins, Lewis C., Soltani, Yashar, Lawson, James R., Slater, Ben, Melen, Rebecca L.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6055811/
https://ncbi.nlm.nih.gov/pubmed/29700863
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201801493
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