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Advanced 1,1-carboboration reactions with pentafluorophenylboranes

The 1,1 carboboration reaction of a variety of metal-substituted alkynes with simple trialkylboranes R(3)B yields the respective alkenylboranes (Wrackmeyer reaction). The use of the strongly electrophilic R-B(C(6)F(5))(2) reagents allows for much milder reaction conditions and gives good yields of t...

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Detaylı Bibliyografya
Yayımlandı:Chem Sci
Asıl Yazarlar: Kehr, Gerald, Erker, Gerhard
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: Royal Society of Chemistry 2016
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC5508682/
https://ncbi.nlm.nih.gov/pubmed/28757997
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03282b
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