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Borane-induced ring closure reaction of oligomethylene-linked bis-allenes
The trimethylene-linked bis-allene 3a reacts with Piers' borane [HB(C(6)F(5))(2)] by a hydroboration/allylboration sequence to generate the cyclization product 5a. Its pyridine adduct was isolated and characterized by X-ray diffraction. Compound 5a undergoes a typical frustrated Lewis pair 1,2-...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8148058/ https://ncbi.nlm.nih.gov/pubmed/34084385 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03870a |
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