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Reactions of an anionic chelate phosphane/borata-alkene ligand with [Rh(nbd)Cl](2), [Rh(CO)(2)Cl](2) and [Ir(cod)Cl](2)
Borata-alkenes can serve as anionic olefin equivalent ligands in transition metal chemistry. A chelate ligand of this type is described and used for metal coordination. Deprotonation of the Mes(2)P(CH(2))(2)B(C(6)F(5))(2) frustrated Lewis pair in the α-CH[B] position gave the methylene-bridged phosp...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7654189/ https://ncbi.nlm.nih.gov/pubmed/33209245 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02223c |
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