Reactions of an anionic chelate phosphane/borata-alkene ligand with [Rh(nbd)Cl](2), [Rh(CO)(2)Cl](2) and [Ir(cod)Cl](2)

Borata-alkenes can serve as anionic olefin equivalent ligands in transition metal chemistry. A chelate ligand of this type is described and used for metal coordination. Deprotonation of the Mes(2)P(CH(2))(2)B(C(6)F(5))(2) frustrated Lewis pair in the α-CH[B] position gave the methylene-bridged phosp...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Watanabe, Kohei, Ueno, Atsushi, Tao, Xin, Škoch, Karel, Jie, Xiaoming, Vagin, Sergei, Rieger, Bernhard, Daniliuc, Constantin G., Letzel, Matthias C., Kehr, Gerald, Erker, Gerhard
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2020
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7654189/
https://ncbi.nlm.nih.gov/pubmed/33209245
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02223c
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