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Vicinal Diamination of Alkenes under Rh-Catalysis
[Image: see text] The synthesis of 1,2-diamines has been achieved through a single-step, tandem sequence involving Rh-catalyzed aziridination followed by NaI-promoted rearrangement to an isomeric cyclic sulfamide. Facile ring opening of these products in hot water and pyridine affords differentially...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4183635/ https://ncbi.nlm.nih.gov/pubmed/25233140 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja506532h |
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