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Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair
The conjugated dienamine 4 selectively adds Piers' borane [HB(C(6)F(5))(2)] to give the enamine/borane system 5, which features a boratirane structure by internal enamine carbon Lewis base to boron Lewis acid interaction. Compound 5 behaves as a C/B frustrated Lewis pair and undergoes typical a...
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| Publicado no: | Philos Trans A Math Phys Eng Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society Publishing
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5540844/ https://ncbi.nlm.nih.gov/pubmed/28739970 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rsta.2017.0015 |
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