CO/CO and NO/NO coupling at a hidden frustrated Lewis pair template

N-Allyltetramethylpiperidine is readily isomerized to the corresponding enamine by treatment with catalytic amounts of B(C(6)F(5))(3). It adds HB(C(6)F(5))(2) at the nucleophilic enamine carbon atom to form a C/B Lewis adduct. This reacts with two molar equivalents of carbon monoxide by selective he...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Wang, Tongdao, Wang, Long, Daniliuc, Constantin G., Samigullin, Kamil, Wagner, Matthias, Kehr, Gerald, Erker, Gerhard
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5369402/
https://ncbi.nlm.nih.gov/pubmed/28451352
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04459j
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