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CO/CO and NO/NO coupling at a hidden frustrated Lewis pair template
N-Allyltetramethylpiperidine is readily isomerized to the corresponding enamine by treatment with catalytic amounts of B(C(6)F(5))(3). It adds HB(C(6)F(5))(2) at the nucleophilic enamine carbon atom to form a C/B Lewis adduct. This reacts with two molar equivalents of carbon monoxide by selective he...
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| Izdano u: | Chem Sci |
|---|---|
| Glavni autori: | , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2017
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5369402/ https://ncbi.nlm.nih.gov/pubmed/28451352 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04459j |
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