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Formation of macrocyclic ring systems by carbonylation of trifunctional P/B/B frustrated Lewis pairs
The trifunctional P/B/B frustrated Lewis pairs 11a–c featuring bulky aryl groups at phosphorus [Dmesp (a), Tipp (b), Mes* (c)] react with H(2) by heterolytic hydrogen splitting followed by cleavage of HB(C(6)F(5))(2) to give the zwitterionic six-membered heterocyclic PH phosphonium/borate products 1...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5890323/ https://ncbi.nlm.nih.gov/pubmed/29675199 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04394e |
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