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Geminal bis-borane formation by borane Lewis acid induced cyclopropyl rearrangement and its frustrated Lewis pair reaction with carbon dioxide
Cyclopropylacetylene reacts with two molar equivalents of Piers' borane [HB(C(6)F(5))(2)] under mild conditions by an addition/rearrangement sequence with cyclopropyl ring opening to give a mixture of two α-B(C(6)F(5))(2) substituted tetrahydroboroles. This compound forms an active frustrated L...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5369401/ https://ncbi.nlm.nih.gov/pubmed/28451249 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc03468c |
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