Solid state frustrated Lewis pair chemistry

In solution the PCy(3)/B(C(6)F(5))(3) pair is rapidly deactivated by nucleophilic aromatic substitution. In the solid state deactivation is effectively suppressed and the active frustrated phosphane/borane Lewis pair splits dihydrogen or adds to sulfur dioxide. A variety of phosphane/B(C(6)F(5))(3)...

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Bibliografiset tiedot
Julkaisussa:Chem Sci
Päätekijät: Wang, Long, Kehr, Gerald, Daniliuc, Constantin G., Brinkkötter, Melanie, Wiegand, Thomas, Wübker, Anna-Lena, Eckert, Hellmut, Liu, Lei, Brandenburg, Jan Gerit, Grimme, Stefan, Erker, Gerhard
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: Royal Society of Chemistry 2018
Aiheet:
Chemistry
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC5982199/
https://ncbi.nlm.nih.gov/pubmed/29910938
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01089g
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