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Solid state frustrated Lewis pair chemistry
In solution the PCy(3)/B(C(6)F(5))(3) pair is rapidly deactivated by nucleophilic aromatic substitution. In the solid state deactivation is effectively suppressed and the active frustrated phosphane/borane Lewis pair splits dihydrogen or adds to sulfur dioxide. A variety of phosphane/B(C(6)F(5))(3)...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5982199/ https://ncbi.nlm.nih.gov/pubmed/29910938 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01089g |
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