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Pd-Catalyzed Aerobic Oxidative Biaryl Coupling: Non-Redox Cocatalysis by Cu(OTf)(2) and Discovery of Fe(OTf)(3) as a Highly Effective Cocatalyst
Copper salts find widespread use in Pd-catalyzed oxidation reactions, and they are typically used as oxidants or redox-active cocatalysts. Here, we probe the origin of a dramatic acceleration effect of Cu(OTf)(2) in the C–H/C–H aerobic oxidative coupling of o-xylene. NMR spectroscopic analysis of th...
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| Izdano u: | J Am Chem Soc |
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| Glavni autori: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2017
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5485668/ https://ncbi.nlm.nih.gov/pubmed/28399364 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b01970 |
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