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Cu/Nitroxyl Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature

An efficient catalytic method has been developed for aerobic oxidation of primary amines to the corresponding nitriles. The reactions proceed at room temperature and employ a catalyst consisting of (4,4′-(t)Bu(2)bpy)CuI/ABNO (ABNO = 9-azabicyclo[3.3.1]nonan-3-one N-oxyl). The reactions exhibit excel...

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Bibliographic Details
Main Authors: Kim, Jinho, Stahl, Shannon S.
Format: Artigo
Language:Inglês
Published: 2013
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3763855/
https://ncbi.nlm.nih.gov/pubmed/24015373
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cs400360e
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