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Cu/Nitroxyl Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature

An efficient catalytic method has been developed for aerobic oxidation of primary amines to the corresponding nitriles. The reactions proceed at room temperature and employ a catalyst consisting of (4,4′-(t)Bu(2)bpy)CuI/ABNO (ABNO = 9-azabicyclo[3.3.1]nonan-3-one N-oxyl). The reactions exhibit excel...

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Detalhes bibliográficos
Main Authors: Kim, Jinho, Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3763855/
https://ncbi.nlm.nih.gov/pubmed/24015373
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cs400360e
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