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Palladium-Catalyzed Aerobic Acetoxylation of Benzene using NO(x)-Based Redox Mediators()
Palladium-catalyzed methods for C–H oxygenation with O(2) as the stoichiometric oxidant are limited. Here, we describe the use of nitrite and nitrate sources as NO(x)-based redox mediators in the acetoxylation of benzene. The conditions completely avoid formation of biphenyl as a side product, and s...
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| Publicado no: | J Organomet Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4379509/ https://ncbi.nlm.nih.gov/pubmed/25843978 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jorganchem.2015.03.003 |
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