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Pd-Catalyzed Aerobic Oxidative Biaryl Coupling: Non-Redox Cocatalysis by Cu(OTf)(2) and Discovery of Fe(OTf)(3) as a Highly Effective Cocatalyst

Copper salts find widespread use in Pd-catalyzed oxidation reactions, and they are typically used as oxidants or redox-active cocatalysts. Here, we probe the origin of a dramatic acceleration effect of Cu(OTf)(2) in the C–H/C–H aerobic oxidative coupling of o-xylene. NMR spectroscopic analysis of th...

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Библиографические подробности
Опубликовано в: :J Am Chem Soc
Главные авторы: Wang, Dian, Stahl, Shannon S.
Формат: Artigo
Язык:Inglês
Опубликовано: 2017
Предметы:
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC5485668/
https://ncbi.nlm.nih.gov/pubmed/28399364
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b01970
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