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Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed C–H Functionalization

An improved method for direct oxidative coupling of o-xylene could provide streamlined access to an important monomer used in polyimide resins. The use of 2-fluoropyridine as a ligand has been found to enable unprecedented levels of chemo- and regioselectivity in this Pd-catalyzed aerobic oxidative...

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Detalhes bibliográficos
Main Authors: Izawa, Yusuke, Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3049937/
https://ncbi.nlm.nih.gov/pubmed/21399704
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201000771
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