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Pd-Catalyzed Aerobic Oxidative Coupling of Thiophenes: Synergistic Benefits of Phenanthroline Dione and a Cu Cocatalyst

Substituted bithiophenes are prominent fragments in functional organic materials, and they are ideally prepared via direct oxidative C–H/C–H coupling. Here, we report a novel Pd(II) catalyst system, employing 1,10-phenanthroline-5,6-dione (phd) as the ancillary ligand, that enables aerobic oxidative...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Tereniak, Stephen J., Bruns, David L., Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8099933/
https://ncbi.nlm.nih.gov/pubmed/33155814
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c09962
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