A 1-hole Cu(4)S cluster with N(2)O reductase activity: a structural and functional model for Cu(Z)*

During bacterial denitrification, two-electron reduction of N(2)O occurs at a [Cu(4)(μ(4)-S)] catalytic site (Cu(Z)*) embedded within the nitrous oxide reductase (N(2)OR) enzyme. In this communication, an amidinate-supported [Cu(4)(μ(4)-S)] model cluster in its 1-hole (S = ½) redox state is thorough...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Johnson, Brittany J., Antholine, William E., Lindeman, Sergey V., Graham, Michael J., Mankad, Neal P.
Format: Artigo
Language:Inglês
Published: 2016
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5378702/
https://ncbi.nlm.nih.gov/pubmed/27685680
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b05480
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