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A Cu(4)S Model for the Nitrous Oxide Reductase Active Sites Supported Only by Nitrogen Ligands()
To model the (His)(7)Cu(4)S(n) (n = 1 or 2) active sites of nitrous oxide reductase, the first Cu(4)(μ(4)-S) cluster supported only by nitrogen donors has been prepared using amidinate supporting ligands. Structural, magnetic, spectroscopic, and computational characterization is reported. Electroche...
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| Publicat a: | Chem Commun (Camb) |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2015
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4731228/ https://ncbi.nlm.nih.gov/pubmed/26111160 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc04675k |
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