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A Cu(4)S Model for the Nitrous Oxide Reductase Active Sites Supported Only by Nitrogen Ligands()

To model the (His)(7)Cu(4)S(n) (n = 1 or 2) active sites of nitrous oxide reductase, the first Cu(4)(μ(4)-S) cluster supported only by nitrogen donors has been prepared using amidinate supporting ligands. Structural, magnetic, spectroscopic, and computational characterization is reported. Electroche...

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Bibliografske podrobnosti
izdano v:Chem Commun (Camb)
Main Authors: Johnson, Brittany J., Antholine, William E., Lindeman, Sergey V., Mankad, Neal P.
Format: Artigo
Jezik:Inglês
Izdano: 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4731228/
https://ncbi.nlm.nih.gov/pubmed/26111160
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc04675k
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