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A 1-hole Cu(4)S cluster with N(2)O reductase activity: a structural and functional model for Cu(Z)*
During bacterial denitrification, two-electron reduction of N(2)O occurs at a [Cu(4)(μ(4)-S)] catalytic site (Cu(Z)*) embedded within the nitrous oxide reductase (N(2)OR) enzyme. In this communication, an amidinate-supported [Cu(4)(μ(4)-S)] model cluster in its 1-hole (S = ½) redox state is thorough...
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| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5378702/ https://ncbi.nlm.nih.gov/pubmed/27685680 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b05480 |
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