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N(2)O Reductase Activity of a [Cu(4)S] Cluster in the 4Cu(I) Redox State Modulated by Hydrogen Bond Donors and Proton Relays in the Secondary Coordination Sphere

The synthetic model complex [Cu(4)S(dppa)(4)](2+) (1, dppa = (Ph(2)P)(2)NH) was found to have N(2)O reductase activity in methanol solvent, mediating the 2H(+)/2e(−) reduction of N(2)O to N(2) + H(2)O in the presence of an exogenous electron donor (CoCp(2)). A stoichiometric product featuring two de...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Hsu, Chia-Wei, Rathnayaka, Suresh C., Islam, Shahidul M., MacMillan, Samantha N., Mankad, Neal P.
Format: Artigo
Sprog:Inglês
Udgivet: 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6940516/
https://ncbi.nlm.nih.gov/pubmed/31661177
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201906327
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