טוען...
N(2)O Reductase Activity of a [Cu(4)S] Cluster in the 4Cu(I) Redox State Modulated by Hydrogen Bond Donors and Proton Relays in the Secondary Coordination Sphere
The synthetic model complex [Cu(4)S(dppa)(4)](2+) (1, dppa = (Ph(2)P)(2)NH) was found to have N(2)O reductase activity in methanol solvent, mediating the 2H(+)/2e(−) reduction of N(2)O to N(2) + H(2)O in the presence of an exogenous electron donor (CoCp(2)). A stoichiometric product featuring two de...
שמור ב:
| הוצא לאור ב: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2019
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6940516/ https://ncbi.nlm.nih.gov/pubmed/31661177 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201906327 |
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