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Multinuclear Cu(I) Clusters Featuring a New Triply Bridging Coordination Mode of Phosphaamidinate Ligands

Phosphabenzamidine [mes-NH-C(Ph)==P-mes) (1) and phosphaformamidine (mes-NH-CH==P-mes) (4) ligands have been synthesized and characterized. The conjugate bases of 1 and 4 coordinate by each bridging three Cu(I) ions, forming hexa- and tetranuclear clusters Cu(6)[mes-N==C(Ph)-P-mes](3)Cl(4)Li(THF)(2)...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Rathnayaka, Suresh C., Lindeman, Sergey V., Mankad, Neal P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6443373/
https://ncbi.nlm.nih.gov/pubmed/30003779
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b01422
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