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Oxidation of a [CU(2)S] Complex by N(2)O and CO(2): Insights into a Role of Tetranuclearity in the Cu(z) Site of Nitrous Oxide Reductase
Oxidation of a [Cu(2)(μ-S)] complex by N(2)O or CO(2) generated a [Cu(2)(μ-SO(4))] product. In the presence of a sulfur trap, a [Cu(2)(μ-O)] species also formed from N(2)O. A [Cu(2)(μ-CS(3))] species derived from CS(2) modeled initial reaction intermediates. These observations indicate that one role...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5785442/ https://ncbi.nlm.nih.gov/pubmed/29333559 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc09067f |
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