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Oxidation of a [CU(2)S] Complex by N(2)O and CO(2): Insights into a Role of Tetranuclearity in the Cu(z) Site of Nitrous Oxide Reductase

Oxidation of a [Cu(2)(μ-S)] complex by N(2)O or CO(2) generated a [Cu(2)(μ-SO(4))] product. In the presence of a sulfur trap, a [Cu(2)(μ-O)] species also formed from N(2)O. A [Cu(2)(μ-CS(3))] species derived from CS(2) modeled initial reaction intermediates. These observations indicate that one role...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
में प्रकाशित:Chem Commun (Camb)
मुख्य लेखकों: Bagherzadeh, Sharareh, Mankad, Neal P.
स्वरूप: Artigo
भाषा:Inglês
प्रकाशित: 2018
विषय:
ऑनलाइन पहुंच:https://ncbi.nlm.nih.gov/pmc/articles/PMC5785442/
https://ncbi.nlm.nih.gov/pubmed/29333559
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc09067f
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