(13)C ENDOR Spectroscopy of Lipoxygenase–Substrate Complexes Reveals the Structural Basis for C–H Activation by Tunneling

[Image: see text] In enzymatic C–H activation by hydrogen tunneling, reduced barrier width is important for efficient hydrogen wave function overlap during catalysis. For native enzymes displaying nonadiabatic tunneling, the dominant reactive hydrogen donor–acceptor distance (DAD) is typically ca. 2...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Horitani, Masaki, Offenbacher, Adam R., Carr, Cody A. Marcus, Yu, Tao, Hoeke, Veronika, Cutsail, George E., Hammes-Schiffer, Sharon, Klinman, Judith P., Hoffman, Brian M.
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2017
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5322796/
https://ncbi.nlm.nih.gov/pubmed/28121140
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11856
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