(13)C ENDOR Spectroscopy of Lipoxygenase–Substrate Complexes Reveals the Structural Basis for C–H Activation by Tunneling

[Image: see text] In enzymatic C–H activation by hydrogen tunneling, reduced barrier width is important for efficient hydrogen wave function overlap during catalysis. For native enzymes displaying nonadiabatic tunneling, the dominant reactive hydrogen donor–acceptor distance (DAD) is typically ca. 2...

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Detaylı Bibliyografya
Yayımlandı:J Am Chem Soc
Asıl Yazarlar: Horitani, Masaki, Offenbacher, Adam R., Carr, Cody A. Marcus, Yu, Tao, Hoeke, Veronika, Cutsail, George E., Hammes-Schiffer, Sharon, Klinman, Judith P., Hoffman, Brian M.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: American Chemical Society 2017
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC5322796/
https://ncbi.nlm.nih.gov/pubmed/28121140
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11856
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