(13)C ENDOR Spectroscopy of Lipoxygenase–Substrate Complexes Reveals the Structural Basis for C–H Activation by Tunneling

[Image: see text] In enzymatic C–H activation by hydrogen tunneling, reduced barrier width is important for efficient hydrogen wave function overlap during catalysis. For native enzymes displaying nonadiabatic tunneling, the dominant reactive hydrogen donor–acceptor distance (DAD) is typically ca. 2...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:J Am Chem Soc
Prif Awduron: Horitani, Masaki, Offenbacher, Adam R., Carr, Cody A. Marcus, Yu, Tao, Hoeke, Veronika, Cutsail, George E., Hammes-Schiffer, Sharon, Klinman, Judith P., Hoffman, Brian M.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: American Chemical Society 2017
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5322796/
https://ncbi.nlm.nih.gov/pubmed/28121140
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11856
Tagiau: Ychwanegu Tag
Dim Tagiau, Byddwch y cyntaf i dagio'r cofnod hwn!

Eitemau Tebyg