(13)C ENDOR Spectroscopy of Lipoxygenase–Substrate Complexes Reveals the Structural Basis for C–H Activation by Tunneling

[Image: see text] In enzymatic C–H activation by hydrogen tunneling, reduced barrier width is important for efficient hydrogen wave function overlap during catalysis. For native enzymes displaying nonadiabatic tunneling, the dominant reactive hydrogen donor–acceptor distance (DAD) is typically ca. 2...

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Bibliografiska uppgifter
I publikationen:J Am Chem Soc
Huvudupphovsmän: Horitani, Masaki, Offenbacher, Adam R., Carr, Cody A. Marcus, Yu, Tao, Hoeke, Veronika, Cutsail, George E., Hammes-Schiffer, Sharon, Klinman, Judith P., Hoffman, Brian M.
Materialtyp: Artigo
Språk:Inglês
Publicerad: American Chemical Society 2017
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5322796/
https://ncbi.nlm.nih.gov/pubmed/28121140
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11856
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