Wordt geladen...
High resolution ENDOR spectroscopy combined with quantum chemical calculations reveals the structure of the nitrogenase Janus intermediate E(4)(4H)
We have shown that the key state in N(2) reduction to two NH(3) by the enzyme nitrogenase is the E(4)(4H), ‘Janus’ intermediate, which has accumulated four [e(−)/H(+)] and is poised to undergo reductive elimination of H(2) coupled to N(2) binding and activation. Initial (1)H and (95)Mo ENDOR studies...
Bewaard in:
| Gepubliceerd in: | J Am Chem Soc |
|---|---|
| Hoofdauteurs: | , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2019
|
| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6956989/ https://ncbi.nlm.nih.gov/pubmed/31310109 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b04474 |
| Tags: |
Voeg label toe
Geen labels, Wees de eerste die dit record labelt!
|