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Reversible Photoinduced Reductive Elimination of H(2) from the Nitrogenase Dihydride State, the E(4)(4H) Janus Intermediate
We recently demonstrated that N(2) reduction by nitrogenase involves the obligatory release of one H(2) per N(2) reduced. These studies focused on the E(4)(4H) ‘Janus intermediate’, which has accumulated four reducing equivalents as two [Fe-H-Fe] bridging hydrides. E(4)(4H) is poised to bind and red...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4773049/ https://ncbi.nlm.nih.gov/pubmed/26788586 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b11650 |
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