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Reversible Photoinduced Reductive Elimination of H(2) from the Nitrogenase Dihydride State, the E(4)(4H) Janus Intermediate

We recently demonstrated that N(2) reduction by nitrogenase involves the obligatory release of one H(2) per N(2) reduced. These studies focused on the E(4)(4H) ‘Janus intermediate’, which has accumulated four reducing equivalents as two [Fe-H-Fe] bridging hydrides. E(4)(4H) is poised to bind and red...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Lukoyanov, Dmitriy, Khadka, Nimesh, Yang, Zhi-Yong, Dean, Dennis R., Seefeldt, Lance C., Hoffman, Brian M.
Format: Artigo
Jezik:Inglês
Izdano: 2016
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4773049/
https://ncbi.nlm.nih.gov/pubmed/26788586
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b11650
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