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Reversible Photoinduced Reductive Elimination of H(2) from the Nitrogenase Dihydride State, the E(4)(4H) Janus Intermediate

We recently demonstrated that N(2) reduction by nitrogenase involves the obligatory release of one H(2) per N(2) reduced. These studies focused on the E(4)(4H) ‘Janus intermediate’, which has accumulated four reducing equivalents as two [Fe-H-Fe] bridging hydrides. E(4)(4H) is poised to bind and red...

詳細記述

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書誌詳細
出版年:J Am Chem Soc
主要な著者: Lukoyanov, Dmitriy, Khadka, Nimesh, Yang, Zhi-Yong, Dean, Dennis R., Seefeldt, Lance C., Hoffman, Brian M.
フォーマット: Artigo
言語:Inglês
出版事項: 2016
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4773049/
https://ncbi.nlm.nih.gov/pubmed/26788586
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b11650
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