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Photoinduced Reductive Elimination of H(2) from the Nitrogenase Dihydride (Janus) State Involves a FeMo-cofactor-H(2) Intermediate
N(2) reduction by nitrogenase involves the accumulation of four reducing equivalents at the active site FeMo-cofactor to form a state with two [Fe-H-Fe] bridging hydrides (denoted E(4)(4H), the Janus intermediate), and we recently demonstrated that the enzyme is activated to cleave the N≡N triple bo...
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| Опубликовано в: : | Inorg Chem |
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| Главные авторы: | , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2017
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5444871/ https://ncbi.nlm.nih.gov/pubmed/28177622 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b02899 |
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